Facile synthesis of well-defined water-soluble polymers via atom transfer radical polymerization in aqueous media at ambient temperature

被引：207

作者：

Wang, XS ^{[1
]}

Lascelles, SF ^{[1
]}

Jackson, RA ^{[1
]}

Armes, SP ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a904691g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monomethoxy-capped oligo(ethylene oxide) methacrylate (OEGMA) is readily polymerised in aqueous media by atom transfer radical polymerisation at 20 degrees C using various initiators; the resulting OEGMA polymers and macromonomers were obtained in high yield (> 95%) within short reaction times and polydispersities were as low as 1.12.

引用

页码：1817 / 1818

页数：2

共 18 条

[1] First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media
Ashford, EJ
Naldi, V
O'Dell, R
Billingham, NC
Armes, SP
[J]. CHEMICAL COMMUNICATIONS, 1999, (14) : 1285 - 1286
[2] Termination kinetics in free-radical bulk copolymerization: The systems dodecyl acrylate dodecyl methacrylate and dodecyl acrylate methyl acrylate
Buback, M
Kowollik, C
[J]. MACROMOLECULES, 1999, 32 (05) : 1445 - 1452
[3] Coca S, 1998, J POLYM SCI POL CHEM, V36, P1417, DOI 10.1002/(SICI)1099-0518(19980715)36:9<1417::AID-POLA9>3.0.CO
[4] 2-P
[5] Monohydroxy terminally functionalised poly(methyl methacrylate) from atom transfer radical polymerisation
Haddleton, DM
Waterson, C
Derrick, PJ
Jasieczek, CB
Shooter, AJ
[J]. CHEMICAL COMMUNICATIONS, 1997, (07) : 683 - 684
[6] Low-temperature living "radical" polymerization (atom transfer polymerization) of methyl methacrylate mediated by copper(I) N-alkyl-2-pyridylmethanimine complexes
Haddleton, DM
Kukulj, D
Duncalf, DJ
Heming, AM
Shooter, AJ
[J]. MACROMOLECULES, 1998, 31 (16) : 5201 - 5205
[7] Synthesis of amphiphilic PS-b-PEG-b-PS by atom transfer radical polymerization
Jankova, K
Chen, XY
Kops, J
Batsberg, W
[J]. MACROMOLECULES, 1998, 31 (02) : 538 - 541
[8] BINUCLEAR COPPER(I) COMPLEXES WHICH REVERSIBLY REACT WITH CO .1. DI-MU-HALOGENO-BIS(2,2'-BIPYRIDINE)DICOPPER(I) AND ITS DERIVATIVES
KITAGAWA, S
MUNAKATA, M
[J]. INORGANIC CHEMISTRY, 1981, 20 (07) : 2261 - 2267
[9] Matyjaszewski K, 1998, J POLYM SCI POL CHEM, V36, P823, DOI 10.1002/(SICI)1099-0518(19980415)36:5<823::AID-POLA15>3.3.CO
[10] 2-D

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