The cyperone route to agarofurans: stereoselective introduction of an hydroxy group at C-4

被引：6

作者：

Boyer, FD ^{[1
]}

Beauhaire, J ^{[1
]}

Ducrot, PH ^{[1
]}

机构：

[1] INRA, Unite Phytopharmacol & Mediateurs Chim, F-78026 Versailles, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(02)00309-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper. the construction of the agarofuran tricyclic ring system bearing an hydroxy group at C-4. with the correct configuration at C-4, is described through the rearrangement of the 4.4a alpha-epox 9-benzoyloxy cyperone derivative 11. readily available from cyperone derivative 5c, under acidic conditions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2851 / 2855

页数：5

共 27 条

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