The LiHg(2(2)Pi(3/2)-X(2)Sigma(+)(1/2)) system

被引：7

作者：

Gruber, D

Li, X

Windholz, L

Gleichmann, MM

Hess, BA

Vezmar, I

Pichler, G

机构：

[1] UNIV BONN,LEHRSTUHL THEORET CHEM,D-53115 BONN,GERMANY

[2] UNIV ZAGREB,INST PHYS,ZAGREB 10000,CROATIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 24期

关键词：

D O I：

10.1021/jp9602078

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 2(2) Pi(3/2)-X(2) Sigma(1/2)(+) band as well as the photochemical formation via excitation of the lithium dimer.

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页码：10062 / 10069

页数：8

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