Molecular systems for light driven hydrogen production

被引：345

作者：

Eckenhoff, William T. ^{[1
]}

Eisenberg, Richard ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 42期

基金：

美国国家科学基金会;

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; STATE REDOX POTENTIALS; ACTIVE-SITE MODEL; PHOTOCATALYTIC WATER REDUCTION; VISIBLE-LIGHT; HOMOGENEOUS CATALYSIS; ELECTROGENERATED CHEMILUMINESCENCE; ARTIFICIAL PHOTOSYNTHESIS; FUNCTIONAL MODELS; METAL-COMPLEXES;

D O I：

10.1039/c2dt30823a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recent work towards the production of hydrogen via reduction of protons is described. Most of the systems examined in this perspective use a molecular chromophore for harvesting visible light, a catalyst, which is reduced by the excited (or reduced) chromophore, and finally a sacrificial electron source to oxidatively or reductively quench the chromophore. The reduced catalyst is then responsible for the reduction of protons resulting in hydrogen evolution. Relevant mechanistic work on this topic is also discussed.

引用

页码：13004 / 13021

页数：18

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