Isolation of the stereoisomers of [{Ru(bpy)(2)}(2){Os(bpy)(2)}(mu-HAT)](6+) (HAT=1,4,5,8,9,12-hexaazatriphenylene; bpy=2,2'-bipyridine)

被引:33
作者
Rutherford, TJ [1 ]
Keene, FR [1 ]
机构
[1] JAMES COOK UNIV N QUEENSLAND,SCH BIOMED & MOL SCI,TOWNSVILLE,QLD 4811,AUSTRALIA
关键词
D O I
10.1021/ic9702532
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The stereoisomers of the trinuclear Ru2Os species [{Ru(bpy)(2)}(2){Os(bpy)(2)}(mu-HAT)](6+) (HAT = 1,4,5,8,9,12-hexaazatriphenylene; bpy =2,2'-bipyridine) have been isolated using a combination of stereoselective syntheses and chromatographic procedures and characterized by NMR and CD spectroscopy.
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页码:3580 / &
页数:3
相关论文
共 13 条
[1]   Luminescent and redox-active polynuclear transition metal complexes [J].
Balzani, V ;
Juris, A ;
Venturi, M ;
Campagna, S ;
Serroni, S .
CHEMICAL REVIEWS, 1996, 96 (02) :759-833
[2]  
Balzani V.S. F., 1991, Supramolecular Photochemistry
[3]   INFLUENCE OF PERIPHERAL LIGANDS ON THE METAL-METAL INTERACTION IN DINUCLEAR METAL-COMPLEXES WITH N-HETEROCYCLIC BRIDGING LIGANDS [J].
GIUFFRIDA, G ;
CAMPAGNA, S .
COORDINATION CHEMISTRY REVIEWS, 1994, 135 :517-531
[4]   SPECTROELECTROCHEMICAL CHARACTERISTICS AND PHOTOPHYSICS OF A SERIES OF RUII COMPLEXES WITH 1,4,5,8,9,12-HEXAAZATRIPHENYLENE - EFFECTS OF POLYCOMPLEXATION [J].
JACQUET, L ;
KIRSCHDEMESMAEKER, A .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (17) :2471-2480
[5]  
KEENE FR, IN PRESS COORD CHEM
[6]   RESONANCE RAMAN-SPECTRA AND SPECTROELECTROCHEMICAL PROPERTIES OF MONOMETALLIC AND POLYMETALLIC RUTHENIUM COMPLEXES WITH 1,4,5,8,9,12-HEXAAZATRIPHENYLENE [J].
KIRSCHDEMESMAEKER, A ;
JACQUET, L ;
MASSCHELEIN, A ;
VANHECKE, F ;
HEREMANS, K .
INORGANIC CHEMISTRY, 1989, 28 (12) :2465-2470
[7]   SYNTHETIC ROUTES TO NEW POLYPYRIDYL COMPLEXES OF OSMIUM(II) [J].
KOBER, EM ;
CASPAR, JV ;
SULLIVAN, BP ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1988, 27 (25) :4587-4598
[8]   CONCERNING THE ELECTRONIC-STRUCTURE OF THE IONS M(BPY)33+ (M = FE, RU, OS - BPY = 2,2'-BIPYRIDINE) [J].
KOBER, EM ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1983, 22 (11) :1614-1616
[9]  
MASSCHELEIN R, 1987, INORG CHIM ACTA, V129, P213
[10]   NEW CHARGE-TRANSFER LUMINESCENT POLYMETALLIC COMPLEXES OF RHODIUM(III), IRIDIUM(III), AND RUTHENIUM(II) WITH THE BRIDGING LIGAND 1,4,5,8,9,12-HEXAAZATRIPHENYLENE [J].
ORTMANS, I ;
DIDIER, P ;
KIRSCHDEMESMAEKER, A .
INORGANIC CHEMISTRY, 1995, 34 (14) :3695-3704