Approach to ideal network formation in free-radical crosslinking copolymerization of benzyl acrylate with 1,6-hexanediol diacrylate

被引：21

作者：

Matsumoto, A ^{[1
]}

Taniguchi, A ^{[1
]}

机构：

[1] Kansai Univ, Fac Engn & High Technol, Dept Appl Chem, Osaka 5648680, Japan

来源：

POLYMER JOURNAL | 1999年 / 31卷 / 09期

关键词：

benzyl acrylate; 1,6-hexanediol diacrylate; ideal network formation; crosslinking; gelation;

D O I：

10.1295/polymj.31.711

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-radical crosslinking copolymerization of benzyl acrylate (BzA) with 1,6-hexanediol diacrylate (HDA) was studied. Weight-average molecular weights (M̄w) and molecular weight distribution (MWD) were measured by size-exclusion chromatography. the Flory-Stockmayer gelation theory suggests that MWD curves should rapidly broaden towards a higher-molecular-weight side with crosslinking reaction leading to ideal network formation governed by theory.

引用

页码：711 / 713

页数：3

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