Speciation analysis of mercury in seawater from the lagoon of Venice by on-line pre-concentration HPLC-ICP-MS

被引：40

作者：

Cairns, W. R. L. ^{[2
]}

Ranaldo, M. ^{[1
]}

Hennebelle, R. ^{[3
]}

Turetta, C. ^{[2
]}

Capodaglio, G. ^{[1
,2
]}

Ferrari, C. F. ^{[3
]}

Dommergue, Aurelien ^{[3
]}

Cescon, P. ^{[1
,2
]}

Barbante, C. ^{[1
,2
]}

机构：

[1] Univ Ca Foscari, Dept Environm Sci, I-30123 Venice, Italy

[2] CNR, Inst Dynam Environm Processes, I-30123 Venice, Italy

[3] Lab Glaciol & Geophys Environm, F-38402 St Martin Dheres, France

来源：

ANALYTICA CHIMICA ACTA | 2008年 / 622卷 / 1-2期

关键词：

mercury; speciation; analysis; high performance liquid; chromatography; inductively coupled plasma-mass spectrometry;

D O I：

10.1016/j.aca.2008.05.048

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学]; 081704 [应用化学];

摘要：

A method based on the coupling of HPLC with ICP-MS with an on-line pre-concentration micro-column has been developed for the analysis of inorganic and methyl mercury in the dissolved phase of natural waters. This method allows the rapid pre-concentration and matrix removal of interferences in complex matrices such as seawater with minimal sampling handling. Detection limits of 0.07 ngL-1 for inorganic mercury and 0.02 ngL-1 for methyl mercury have been achieved allowing the determination of inorganic mercury and methyl mercury in filtered seawater from the Venice lagoon. Good accuracy and reproducibility was demonstrated by the repeat a-..,lalysis of the certified reference material BCR-S79 coastal seawater. The developed HPLC separation was shown to be also suitable for the determination of methyl mercury in extracts of the particulate phase. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：62 / 69

页数：8

共 22 条

[1]

SPECIATION OF INORGANIC MERCURY(II) AND METHYLMERCURY BY VESICLE-MEDIATED HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY COUPLED TO COLD VAPOR ATOMIC-ABSORPTION SPECTROMETRY [J].

AIZPUN, B ;

FERNANDEZ, ML ;

BLANCO, E ;

SANZMEDEL, A .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (11) :1279-1284

[2]

Field sampling, preconcentration and determination of mercury species in river waters [J].

Blanco, RM ;

Villanueva, MT ;

Uría, JES ;

Sanz-Medel, A .

ANALYTICA CHIMICA ACTA, 2000, 419 (02) :137-144

[3]

Seasonal cycling of mercury and monomethyl mercury in the Venice Lagoon (Italy) [J].

Bloom, NS ;

Moretto, LM ;

Scopece, P ;

Ugo, P .

MARINE CHEMISTRY, 2004, 91 (1-4) :85-99

[4]

Determination of mercury species in sea-water by liquid chromatography with inductively coupled plasma mass spectrometric detection [J].

Bloxham, MJ ;

Gachanja, A ;

Hill, SJ ;

Worsfold, PJ .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (02) :145-148

[5]

Determination of organomercury compounds in aqueous samples by capillary gas chromatography atomic fluorescence spectrometry following solid-phase extraction [J].

Cai, Y ;

Jaffe, R ;

Alli, A ;

Jones, RD .

ANALYTICA CHIMICA ACTA, 1996, 334 (03) :251-259

[6]

Method optimization for the determination of four mercury species by micro-liquid chromatography-inductively coupled plasma mass spectrometry coupling in environmental water samples [J].

Castillo, A. ;

Roig-Navarro, A. F. ;

Pozo, O. J. .

ANALYTICA CHIMICA ACTA, 2006, 577 (01) :18-25

[7]

A comparison of alkyl derivatization methods for speciation of mercury based on solid phase microextraction gas chromatography with furnace atomization plasma emission spectrometry detection [J].

Grinberg, P ;

Campos, RC ;

Mester, Z ;

Sturgeon, RE .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2003, 18 (08) :902-909

[8]

Sample collection, filtration and preservation protocols for the determination of 'total dissolved' mercury in waters [J].

Hall, GEM ;

Pelchat, JC ;

Pelchat, P ;

Vaive, JE .

ANALYST, 2002, 127 (05) :674-680

[9]

The speciation of mercury and organomercury compounds by using high-performance liquid chromatography [J].

Harrington, CF .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2000, 19 (2-3) :167-179

[10]

Determination of methylmercury and estimation of total mercury in seafood using high performance liquid chromatography (HPLC) and inductively coupled plasma-mass spectrometry (ICP-MS): Method development and validation [J].

Hight, Susan C. ;

Cheng, John .

ANALYTICA CHIMICA ACTA, 2006, 567 (02) :160-172

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