Acetoxylation of camphene catalysed by beta zeolite

被引：18

作者：

Castanheiro, J. E. ^{[1
]}

Fonseca, I. M. ^{[2
]}

Ramos, A. M. ^{[2
]}

Vital, J. ^{[2
]}

机构：

[1] Univ Evora, Dept Quim, Ctr Quim Evora, P-7000671 Evora, Portugal

[2] Univ Nova Lisboa, Fac Ciencias & Tecnol, REQUIMTE CQFB, P-2829516 Caparica, Portugal

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 13期

关键词：

camphene; isobornyl acetate; acetoxylation; beta zeolite;

D O I：

10.1016/j.catcom.2008.05.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Beta zeolite with Si/Al ratio equal to 40 was synthesised and used as solid catalyst in acetoxylation of camphene. The main product of camphene acetoxylation was isobornyl acetate being also formed bornyl acetate and fenchyl acetate. Effects of various parameters, such as reactant molar ratio, reaction temperature, catalysts loading and reusability of the catalyst were studied to optimise the reaction conditions. The catalytic stability of beta zeolite in the acetoxylation of camphene was studied by performing consecutive batch runs with the same catalyst sample. After the third run, it was observed similar values of the catalytic activity. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2205 / 2208

页数：4

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