Wintertime aerosol chemical composition and source apportionment of the organic fraction in the metropolitan area of Paris

被引：328

作者：

Crippa, M. ^{[1
]}

DeCarlo, P. F. ^{[1
]}

Slowik, J. G. ^{[1
]}

Mohr, C. ^{[1
]}

Heringa, M. F. ^{[1
]}

Chirico, R. ^{[1
]}

Poulain, L. ^{[2
]}

Freutel, F. ^{[3
]}

Sciare, J. ^{[4
]}

Cozic, J. ^{[5
]}

Di Marco, C. F. ^{[6
]}

Elsasser, M. ^{[7
,8
]}

Nicolas, J. B. ^{[4
]}

Marchand, N. ^{[9
]}

Abidi, E. ^{[9
]}

Wiedensohler, A. ^{[2
]}

Drewnick, F. ^{[3
]}

Schneider, J. ^{[3
]}

Borrmann, S. ^{[3
,10
]}

Nemitz, E. ^{[6
]}

Zimmermann, R. ^{[7
,8
]}

Jaffrezo, J-L ^{[5
]}

Prevot, A. S. H. ^{[1
]}

Baltensperger, U. ^{[1
]}

机构：

[1] Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland

[2] Leibniz Inst Tropospher Res, D-04318 Leipzig, Germany

[3] Max Planck Inst Chem, Particle Chem Dept, D-55128 Mainz, Germany

[4] UVSQ, CNRS, Lab CEA, LSCE,IPSL, F-91191 Gif Sur Yvette, France

[5] UJF Grenoble 1, CNRS, UMR5183, LGGE, F-38041 Grenoble, France

[6] Ctr Ecol & Hydrol, Penicuik EH26 0QB, Midlothian, Scotland

[7] Helmholtz Zentrum Munchen, Cooperat Grp Comprehens Mol Analyt, Joint Mass Spectrometry Ctr, D-85764 Neuherberg, Germany

[8] Univ Rostock, Inst Chem, Lehrstuhl Analyt Chem, Joint Mass Spectrometry Ctr, D-18059 Rostock, Germany

[9] Aix Marseille Univ, CNRS, LCE FRE 3416, F-13331 Marseille, France

[10] Johannes Gutenberg Univ Mainz, Inst Atmospher Phys, D-55122 Mainz, Germany

来源：

ATMOSPHERIC CHEMISTRY AND PHYSICS | 2013年 / 13卷 / 02期

基金：

瑞士国家科学基金会; 美国国家科学基金会;

关键词：

POSITIVE MATRIX FACTORIZATION; NEW-YORK-CITY; HIGH-RESOLUTION; MASS-SPECTROMETER; ELEMENTAL CARBON; LIGHT-ABSORPTION; PARTICLE COMPOSITION; MOLECULAR MARKERS; MS MEASUREMENTS; AIR-QUALITY;

D O I：

10.5194/acp-13-961-2013

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The effect of a post-industrial megacity on local and regional air quality was assessed via a month-long field measurement campaign in the Paris metropolitan area during winter 2010. Here we present source apportionment results from three aerosol mass spectrometers and two aethalometers deployed at three measurement stations within the Paris region. Submicron aerosol composition is dominated by the organic fraction (30-36%) and nitrate (28-29%), with lower contributions from sulfate (14-16%), ammonium (12-14%) and black carbon (7-13%). Organic source apportionment was performed using positive matrix factorization, resulting in a set of organic factors corresponding both to primary emission sources and secondary production. The dominant primary sources are traffic (11-15% of organic mass), biomass burning (13-15%) and cooking (up to 35% during meal hours). Secondary organic aerosol contributes more than 50% to the total organic mass and includes a highly oxidized factor from indeterminate and/or diverse sources and a less oxidized factor related to wood burning emissions. Black carbon was apportioned to traffic and wood burning sources using a model based on wavelength-dependent light absorption of these two combustion sources. The time series of organic and black carbon factors from related sources were strongly correlated. The similarities in aerosol composition, total mass and temporal variation between the three sites suggest that particulate pollution in Paris is dominated by regional factors, and that the emissions from Paris itself have a relatively low impact on its surroundings.

引用

页码：961 / 981

页数：21

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