A new reactor for industrial organic electrosynthesis

被引：7

作者：

Roquero, P

GhanemLakhal, A

Cognet, P

Lacoste, G

Berlan, J

Fabre, PL

Duverneuil, P

机构：

[1] ENSIGC,LAB SYNTH ORGAN MILIEUX POLYPHAS,F-31078 TOULOUSE,FRANCE

[2] UNIV TOULOUSE 3,CHIM INORGAN LAB,F-31062 TOULOUSE,FRANCE

来源：

CHEMICAL ENGINEERING SCIENCE | 1996年 / 51卷 / 10期

关键词：

D O I：

10.1016/0009-2509(96)00042-5

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The Pulsated Percolated Porous Electrode reactor (E3P), designed for heavy metals recovery from industrial waste waters, has been successfully adapted to some organic electrosynthesis applications. This is possible because of the high electrode surface areas and good transfer coefficients that can be obtained by this process. An industrial organic electrosynthesis pilot plant has been built following the principles of the initial laboratory scale reactor. The indirect oxidation of cyclohexanol in an aqueous solution and the reduction of acetophenone in a two phase liquid - liquid medium are studied. The results show the capacities and flexibility of this new reactor for applications in the industrial organic synthesis field.

引用

页码：1847 / 1855

页数：9

共 10 条

[1]

Bard A.J., 1983, ELECTROCHIMIE PRINCI

[2]

BROWN D, 1977, LIEBIGS ANN CHEM, P77

[3] ELECTROCATALYTIC REDUCTION USING RANEY-NICKEL [J].