A Conducting Coordination Polymer Based on Assembled Cu9 Cages

被引：95

作者：

Delgado, Salome ^{[1
]}

Miguel, Pablo J. Sanz ^{[1
]}

Priego, Jose L. ^{[2
]}

Jimenez-Aparicio, Reyes ^{[2
]}

Gomez-Garcia, Carlos J. ^{[3
]}

Zamora, Felix ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Inorgan, E-28049 Madrid, Spain

[2] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain

[3] Univ Valencia, ICMol Parque Cient, Valencia, Spain

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 20期

关键词：

D O I：

10.1021/ic801314s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report on a novel highly semiconducting 1D coordination polymer architecture obtained by the reaction of a Cull salt with 2,2'-dipyridyldisulfide under microwave solvothermal conditions. This reaction proceeds with an unusual C-S and S-S bond cleavage of the 2,2'-dipyridyldisulfide ligand. The unprecedented architecture of this coordination polymer consists of a 1D chain formed by the assembling of Cu-9 cluster cages. The electrical conductivity behavior of this novel material suggests new perspectives for the use of coordination polymers as electrical conducting materials.

引用

页码：9128 / 9130

页数：3

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