Polylactic acid coating on a biodegradable magnesium alloy: An in vitro degradation study by electrochemical impedance spectroscopy

被引:125
作者
Alabbasi, Alyaa [1 ]
Liyanaarachchi, S. [1 ]
Kannan, M. Bobby [1 ]
机构
[1] James Cook Univ, Sch Engn & Phys Sci, Discipline Chem Engn, Townsville, Qld 4811, Australia
关键词
Polylactic acid; Magnesium alloy; Biomaterials; Biodegradation; MECHANICAL INTEGRITY; CORROSION; BEHAVIOR; POLYMERS;
D O I
10.1016/j.tsf.2012.07.090
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
Polylactic acid (PLA) was coated on a biodegradable magnesium alloy, AZ91, using spin coating technique for temporary implant applications. The degradation behaviour of the coated alloy samples was evaluated using electrochemical impedance spectroscopy (EIS) method in simulated body fluid (SBF). EIS results suggested that the PLA coating enhanced the degradation resistance of the alloy significantly. Increase in the PLA coating thickness was found to increase the degradation resistance, but resulted in poor adhesion. Long-term EIS experiments of the PLA coated samples suggested that their degradation resistance gradually decreased with increase in SBF exposure time. However, the degradation resistance of the PLA coated samples was significantly higher than that of the bare metal even after a 48 h exposure to SBF. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:6841 / 6844
页数:4
相关论文
共 22 条
[1]
Undoped polyaniline anticorrosive properties [J].
Araujo, WS ;
Margarit, ICP ;
Ferreira, M ;
Mattos, OR ;
Neto, PL .
ELECTROCHIMICA ACTA, 2001, 46 (09) :1307-1312
[2]
Interaction between a high purity magnesium surface and PCL and PLA coatings during dynamic degradation [J].
Chen, Ying ;
Song, Yang ;
Zhang, Shaoxiang ;
Li, Jianan ;
Zhao, Changli ;
Zhang, Xiaonong .
BIOMEDICAL MATERIALS, 2011, 6 (02)
[3]
EIS behavior of anodized zinc in chloride environments [J].
Chung, SC ;
Cheng, JR ;
Chiou, SD ;
Shih, HC .
CORROSION SCIENCE, 2000, 42 (07) :1249-1268
[4]
TISSUE-RESPONSE AND IN-VIVO DEGRADATION OF SELECTED POLYHYDROXYACIDS - POLYLACTIDES (PLA), POLY(3-HYDROXYBUTYRATE) (PHB), AND POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE) (PHB/VA) [J].
GOGOLEWSKI, S ;
JOVANOVIC, M ;
PERREN, SM ;
DILLON, JG ;
HUGHES, MK .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1993, 27 (09) :1135-1148
[5]
Excimer laser surface treatment of magnesium alloy WE43 for corrosion resistance improvement [J].
Guo, LF ;
Yue, TM ;
Man, HC .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (13) :3531-3533
[6]
New emerging trends in synthetic biodegradable polymers - Polylactide: A critique [J].
Gupta, A. P. ;
Kumar, Vimal .
EUROPEAN POLYMER JOURNAL, 2007, 43 (10) :4053-4074
[7]
Fabrication and characterization of block copolymer micelle multilayer films prepared using dip-, spin- and spray-assisted layer-by-layer assembly deposition [J].
Hong, Jinkee ;
Park, HoSeok .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2011, 381 (1-3) :7-12
[8]
Electrochemical impedance spectroscopy evaluation of the corrosion behavior of die cast and thixocast AXJ530 magnesium alloy in chloride solution [J].
Jin, Shize ;
Amira, Sofiene ;
Ghali, Edward .
ADVANCED ENGINEERING MATERIALS, 2007, 9 (1-2) :75-83
[9]
In vitro degradation and mechanical integrity of calcium-containing magnesium alloys in modified-simulated body fluid [J].
Kannan, M. Bobby ;
Raman, R. K. Singh .
BIOMATERIALS, 2008, 29 (15) :2306-2314
[10]
Influence of circumferential notch and fatigue crack on the mechanical integrity of biodegradable magnesium-based alloy in simulated body fluid [J].
Kannan, M. Bobby ;
Raman, R. K. Singh ;
Witte, F. ;
Blawert, C. ;
Dietzel, W. .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2011, 96B (02) :303-309