Gold based bimetallic catalysts for liquid phase applications

被引：21

作者：

Dimitratos, N

Prati, L

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Met & Analit, I-20133 Milan, Italy

[2] Univ Milan, Ctr CNR, AURICAT Programme, Ctr Excellence,CIMAINA Unit, I-20133 Milan, Italy

来源：

GOLD BULLETIN | 2005年 / 38卷 / 02期

关键词：

D O I：

10.1007/BF03215236

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The liquid phase oxidation of D-Sorbitol has been carried out in water using oxygen as the oxidant in the presence of gold based catalyst. Au/C, Pt/C and Pd/C monometallic systems were compared to bimetallic Au/Pd and Au/Pt on carbon. A strong synergistic effect was observed producing a significant increase of reaction rate. Moreover, the addition of gold to Pd or Pt catalyst produced a system more resistant to oxygen poisoning allowing it to work also under a moderate pressure. The effect of varying the molar ratio of the metals has also been studied.

引用

页码：73 / 77

页数：5

共 19 条

[1] Complete oxidation of benzene over Au-V2O5/TiO2 and Au-V2O5/ZrO2 catalysts [J].