Preparation and Characterization of Graphene Oxide/Poly(vinyl alcohol) Composite Nanofibers via Electrospinning

被引:103
作者
Wang, Chen [1 ,2 ]
Li, Yadong [1 ]
Ding, Guqiao [2 ]
Xie, Xiaoming [2 ]
Jiang, Mianheng [2 ]
机构
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China
关键词
graphene oxide; electrospinning; nanofiber; composite; poly(vinyl alcohol); tensile strength; NANOCOMPOSITES; OXIDE; FIBERS; FILMS;
D O I
10.1002/app.37656
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
Graphene oxide (GO) was well dispersed in poly(vinyl alcohol) (PVA) diluted aqueous solution, and then the mixture was electrospun into GO/PVA composite nanofibers. Electron microscopy and Raman spectroscopy on the as-prepared and calcined samples confirm the uniform distribution of GO sheets in the nanofibers. The thermal and mechanical properties of the nanofibers vary considerably with different GO filler contents. The decomposition temperatures of the GO/PVA composite nanofiber dropped by 38-50 degrees C compared with pure PVA. A very small loading of 0.02 wt % GO increases the tensile strength of the nanofibers by 42 times. A porous 3D structure was realized by postcalcining nanofibers in H-2. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 127: 3026-3032, 2013
引用
收藏
页码:3026 / 3032
页数:7
相关论文
共 37 条
[1]
Graphene-Polymer Nanofiber Membrane for Ultrafast Photonics [J].
Bao, Qiaoliang ;
Zhang, Han ;
Yang, Jia-xiang ;
Wang, Shuai ;
Tong, Ding Yuan ;
Jose, Rajan ;
Ramakrishna, Seeram ;
Lim, Chwee Teck ;
Loh, Kian Ping .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (05) :782-791
[2]
Beachley V., 2011, J PROG POLYM SCI, V35, P868
[3]
Sepiolite needle-like clay for PA6 nanocomposites: An alternative to layered silicates? [J].
Bilotti, E. ;
Zhang, R. ;
Deng, H. ;
Quero, F. ;
Fischer, H. R. ;
Peijs, T. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (15-16) :2587-2595
[4]
Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[5]
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite [J].
Cote, Laura J. ;
Cruz-Silva, Rodolfo ;
Huang, Jiaxing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :11027-11032
[6]
Formalas A., 1934, US Patent, Patent No. [1975504, US1975504A]
[7]
Poly[2,6-(1,4-phenylene)-benzobisimidazole] Nanofiber Networks [J].
Gong, Jin ;
Uchida, Tetsuya ;
Yamazaki, Shinichi ;
Kimura, Kunio .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (20) :2226-2232
[8]
Effect of amino acid sequence and pH on nanofiber formation of self-assembling peptides EAK16-II and EAK16-IV [J].
Hong, YS ;
Legge, RL ;
Zhang, S ;
Chen, P .
BIOMACROMOLECULES, 2003, 4 (05) :1433-1442
[9]
Changing the dielectric properties of BaTiO3 filled poly(phenylene oxide) composites by control of their structure [J].
Jang, Yong Kyun ;
Won, Jong Chan ;
Yoon, Ho Gyu .
APPLIED PHYSICS LETTERS, 2009, 95 (05)
[10]
Mechanical properties of electrospun PVA/MWNTs composite nanofibers [J].
Jeong, J. S. ;
Moon, J. S. ;
Jeon, S. Y. ;
Park, J. H. ;
Alegaonkar, P. S. ;
Yoo, J. B. .
THIN SOLID FILMS, 2007, 515 (12) :5136-5141