Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides

被引：72

作者：

Guerrero, G

Mehring, M

Mutin, PH

Dahan, F

Vioux, A

机构：

[1] Univ Montpellier 2, CNRS, UMR 5637, F-34095 Montpellier 5, France

[2] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 4, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 10期

关键词：

D O I：

10.1039/a902407g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of PhP(O)(OH)(2) or Ph2P(O)OH with Ti(OPri)(4) in DMSO give the soluble tetranuclear complexes [Ti-4(mu(3)-O)(OPri)(5)(mu-OPri)(3)(PhPO3)(3)]. DMSO 1 or [Ti(mu(3)-O)(OPri)(Ph2PO2)](4). 0.5DMSO 2, the first examples of phosphonato- and phosphinato-bridged titanium oxo alkoxides, which have been characterised by single-crystal X-ray diffraction.

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页码：1537 / 1538

页数：2

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