Resonant excitation energy transfer in [Rh(bpy)(3)][NaCr(ox)(3)]ClO4

被引：26

作者：

Hauser, A

Riesen, H

Pellaux, R

Decurtins, S

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

[2] UNIV ZURICH,INST ANORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 261卷 / 03期

关键词：

D O I：

10.1016/0009-2614(96)00969-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Resonant fluorescence line narrowing of the R(1) line of the [Cr(ox)(3)](3-) chromophore in [Rh(bpy)(3)][NaCr(ox)(3)]ClO4 at 1.6 K neither gives rise to the usual three-line pattern nor to spectral diffusion. Instead multi-line spectra with spacings equal to the zero-field splitting of the ground state are observed. This phenomenon is attributed to efficient non-radiative resonant energy transfer within the R(1) line.

引用

页码：313 / 317

页数：5

共 17 条

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[2]

BLASSE G, 1984, NATO ASI B, V114, P251

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