Facile and stereoselective synthesis of vinylphosphonates

被引：50

作者：

Cristau, HJ

Mbianda, XY

Beziat, Y

Gasc, MB

机构：

[1] Lab. Chim. Organique ENSCM (U. R.), 34053 Montpellier Cédex 1

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 529卷 / 1-2期

关键词：

phosphonates; stereoselective synthesis; hydrogenation; cuprate addition; vinylphosphonates;

D O I：

10.1016/S0022-328X(96)06646-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereoselective syntheses of mono-, di- and trisubstituted diethyl alk-1-enylphosphonates, starting from readily available alk-1-ynylphosphonates, have been developed, using catalytic hydrogenation or cuprate addition on the triple bond.

引用

页码：301 / 311

页数：11

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