Hydrothermally stable ordered hexagonal mesoporous aluminosilicates assembled from a triblock copolymer and preformed aluminosilicate precursors in strongly acidic media

被引:193
作者
Han, Y
Wu, S
Sun, YY
Li, DS
Xiao, FS [1 ]
Liu, J
Zhang, XZ
机构
[1] Tsinghua Univ, Dept Mat Sci, Beijing 100084, Peoples R China
[2] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China
关键词
D O I
10.1021/cm010633s
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous aluminosilicates (MAS-9) with ordered hexagonal struture have been prepared by assembly of preformed aluminosilicate precursors with a triblock copolymer in strongly acidic media by a two-step procedure. MAS-9 exhibits extraordinarily good hydrothermal stability and high catalytic activities for the cracking of both cumene and 1,3,5-tri-isopropylbenzene. Even after treatment in boiling water for 120 h, MAS-9 continues to show a large surface area (680 m(2)/g) and high catalytic activities. Furthermore, this two-step strategy could be used as a new general method for the preparation of mesoporous aluminosilicate materials under strongly acidic conditions.
引用
收藏
页码:1144 / 1148
页数:5
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