Highly Efficient Organic Light-Emitting Diode Based on a Hidden Thermally Activated Delayed Fluorescence Channel in a Heptazine Derivative

被引:640
作者
Li, Jie [1 ,2 ]
Nakagawa, Tetsuya [1 ,2 ]
MacDonald, James [1 ,2 ,3 ]
Zhang, Qisheng [1 ,2 ]
Nomura, Hiroko [1 ,2 ]
Miyazaki, Hiroshi [1 ,2 ,4 ]
Adachi, Chihaya [1 ,2 ,5 ]
机构
[1] Kyushu Univ, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Ctr Organ Photon & Elect Res OPERA, Nishi Ku, Fukuoka 8190395, Japan
[3] CSIRO, Mat Sci & Engn, Clayton, Vic 3168, Australia
[4] Nippon Steel & Sumikin Chem Co Ltd, Funct Mat Lab, Kitakyushu, Fukuoka 8048503, Japan
[5] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Fukuoka 8190395, Japan
关键词
organic light-emitting diode; thermally activated delayed fluorescence; heptazine; orange-red device; EXTERNAL QUANTUM EFFICIENCY; COMPLEXES; GREEN; PHOSPHORS; EMISSION; DEVICES; DESIGN;
D O I
10.1002/adma.201300575
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
An orange-red organic light-emitting diode containing a heptazine derivative exhibits high performance with a maximum external quantum efficiency of 17.5 ± 1.3% and a peak luminance of 17000 ± 1600 cd m -2 without any light out-coupling enhancement. The high electroluminescence performance can be ascribed to the presence of an efficient up-conversion channel from the lowest triplet state to the lowest singlet state. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3319 / 3323
页数:5
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