A new approach to surface properties of solid electrolyte interphase on a graphite negative electrode

被引：51

作者：

Lee, Seon-Hong ^{[1
]}

You, Ho-Gon ^{[1
]}

Han, Kyu-Suk ^{[1
]}

Kim, Jake ^{[1
]}

Jung, In-Ho ^{[1
]}

Song, Joo-Han ^{[1
]}

机构：

[1] Samsung SDI Co Ltd, Corp R&D Ctr, Yongin 446577, Gyunggido, South Korea

来源：

JOURNAL OF POWER SOURCES | 2014年 / 247卷

关键词：

Lithium-ion battery; Graphite; Solid electrolyte interphase; Low acceleration voltage; Monte Carlo simulation; Ion etching; PROPYLENE CARBONATE; LI-ION; ELECTROCHEMICAL-BEHAVIOR; LITHIUM INTERCALATION; SEM; MICROSCOPY; ADDITIVES; BATTERIES; MECHANISM;

D O I：

10.1016/j.jpowsour.2013.08.105

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

A new method for observing the outermost surface morphology and the thickness of solid electrolyte interphase (SEI) are presented. Low acceleration voltage in extreme high resolution scanning electron microscopy (XHR-SEM) provides detailed information on the SEI surface morphology due to secondary electron contrast mechanism. Also, XHR-SEM under low acceleration voltage with low energy induced ion etching in x-ray photoelectron spectroscopy (XPS) studies provides valuable information on the SEI layer thickness. More detailed properties of the SEI layer were investigated by transmission electron microscopy (TEM). (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：307 / 313

页数：7

共 40 条

[1]

Functional electrolyte: Additives for improving the cyclability of cathode materials [J].

Abe, K ;

Takaya, T ;

Yoshitake, H ;

Ushigoe, Y ;

Yoshio, M ;

Wang, HY .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (12) :A462-A465

[2]

Additives-containing functional electrolytes for suppressing electrolyte decomposition in lithium-ion batteries [J].

Abe, K ;

Yoshitake, H ;

Kitakura, T ;

Hattori, T ;

Wang, HY ;

Yoshio, M .

ELECTROCHIMICA ACTA, 2004, 49 (26) :4613-4622

[3]

Chemical composition and morphology of the elevated temperature SEI on graphite [J].

Andersson, AM ;

Edström, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (10) :A1100-A1109

[4]

Surface characterization of electrodes from high power lithium-ion batteries [J].

Andersson, AM ;

Abraham, DP ;

Haasch, R ;

MacLaren, S ;

Liu, J ;

Amine, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (10) :A1358-A1369

[5]

Electrochemically lithiated graphite characterised by photoelectron spectroscopy [J].

Andersson, AM ;

Henningson, A ;

Siegbahn, H ;

Jansson, U ;

Edström, K .

JOURNAL OF POWER SOURCES, 2003, 119 :522-527

[6]

ANDERSSON AM, 2001, SURFACE PHENOMENA LI

[7]

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries [J].

Aurbach, D ;

Markovsky, B ;

Weissman, I ;

Levi, E ;

Ein-Eli, Y .

ELECTROCHIMICA ACTA, 1999, 45 (1-2) :67-86

[8]

THE STUDY OF ELECTROLYTE-SOLUTIONS BASED ON ETHYLENE AND DIETHYL CARBONATES FOR RECHARGEABLE LI BATTERIES .2. GRAPHITE-ELECTRODES [J].

AURBACH, D ;

EINELI, Y ;

MARKOVSKY, B ;

ZABAN, A ;

LUSKI, S ;

CARMELI, Y ;

YAMIN, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (09) :2882-2890

[9]

On the use of vinylene carbonate (VC) electrolyte solutions for Li-ion as an additive to batteries [J].

Aurbach, D ;

Gamolsky, K ;

Markovsky, B ;

Gofer, Y ;

Schmidt, M ;

Heider, U .

ELECTROCHIMICA ACTA, 2002, 47 (09) :1423-1439

[10]

IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS [J].

AURBACH, D ;

DAROUX, ML ;

FAGUY, PW ;

YEAGER, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (07) :1611-1620

← 1 2 3 4 →