Absolute configuration and electronic state properties of light-switch complex [Ru(phen)2dppz]2+ deduced from oriented circular dichroism in a lamellar liquid crystal host

被引：12

作者：

Ardhammar, M

Lincoln, P

Rodger, A

Nordén, B ^{[1
]}

机构：

[1] Univ Gothenburg, Dept Phys Chem, SE-41296 Gothenburg, Sweden

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[3] Chalmers Univ Technol, Dept Phys Chem, SE-41296 Gothenburg, Sweden

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 354卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)00097-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Circular dichroism (CD) of enantiomers of [Ru(phen)(2)dppz](2+) oriented in a octanoate-decanol-water lamellar liquid crystal has been measured parallel to the orientation axis. where the sample does not exhibit linear dichroism (LD). At an inclined incidence, the emerging LD shows that the chromophores have an along-chain orientation in the liquid crystal. The changes in the CD spectrum compared to an isotropic sample, in conjunction with CD calculations, allow us to assess the absolute configuration of the enantiomers and assign the CD bands to specific electronic transitions. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：44 / 50

页数：7

共 18 条

[1]

[Anonymous], SPECTROSCOPY POLARIZ

[2] Ligand substituents of ruthenium dipyridophenazine complexes sensitively determine orientation in liposome membrane [J].