Synthesis of silylated β-enaminones and applications to the synthesis of silyl heterocycles

被引：28

作者：

Calvo, LA ^{[1
]}

González-Nogal, AM ^{[1
]}

González-Ortega, A ^{[1
]}

Sañudo, MC ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, Dept Quim Organ, Valladolid 47011, Spain

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 51期

关键词：

silicon; 2-aminopyrimidines; silicon beta-enaminones; silicon pyrazoles; 2-pyridones; silicon pyrroles;

D O I：

10.1016/S0040-4039(01)01966-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silyl beta -enaminones have been synthesized by reductive cleavage of sitylisoxazoles. These versatile synthons bearing the silyl group in different positions of the enamino ketonic system are of great interest in the construction of a variety of penta- and hexaheterocycles. which, in general, retain the silyl group attached at the ring or in a side chain. (C) 2001 Elsevier Science Ltd, All rights reserved.

引用

页码：8981 / 8984

页数：4

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