Visible-Light-Promoted C-C Bond Cleavage: Photocatalytic Generation of Iminium Ions and Amino Radicals

被引：128

作者：

Cai, Shunyou ^{[1
]}

Zhao, Xinyang ^{[1
]}

Wang, Xinbo ^{[1
]}

Liu, Qisong ^{[1
]}

Li, Zigang ^{[1
]}

Wang, David Zhigang ^{[1
]}

机构：

[1] Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Key Lab Chem Genom, Shenzhen 518055, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 32期

基金：

中国国家自然科学基金;

关键词：

amines; C-C activation; photochemistry; radicals; ruthenium; PHOTOREDOX CATALYSIS; H FUNCTIONALIZATION; POLYMERIZATION REACTIONS; CYCLOADDITIONS; ORGANOCATALYSIS; ALDEHYDES; STRATEGY; TRIFLUOROMETHYLATION; CONSTRUCT; HALIDES;

D O I：

10.1002/anie.201202880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C-C bonds in simple vicinal diamine precursors under very mild reaction conditions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8050 / 8053

页数：4

共 61 条

[1] Andrews R.S., 2010, ANGEW CHEM, V122, P7432
[2] Investigating the Rate of Photoreductive Glucosyl Radical Generation
Andrews, R. Stephen
Becker, Jennifer J.
Gagne, Michel R.
[J]. ORGANIC LETTERS, 2011, 13 (09) : 2406 - 2409
[3] Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light
Andrews, R. Stephen
Becker, Jennifer J.
Gagne, Michel R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (40) : 7274 - 7276
[4] Brazier JB, 2009, TOP CURR CHEM, V291, P281, DOI [10.1007/128_2008_28, 10.1007/978-3-642-02815-1_28]
[5] Ciamician G, 1912, Science, V36, P385, DOI 10.1126/science.36.926.385
[6] Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C-H Functionalization
Condie, Allison G.
Gonzalez-Gomez, Jose C.
Stephenson, Corey R. J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) : 1464 - +
[7] Visible-light-mediated conversion of alcohols to halides
Dai, Chunhui
Narayanam, Jagan M. R.
Stephenson, Corey R. J.
[J]. NATURE CHEMISTRY, 2011, 3 (02) : 140 - 145
[8] New developments in photoinitiators
Dietliker, K
Jung, TJ
Benkhoff, J
Kura, H
Matsumoto, A
Oka, H
Hristova, D
Gescheidt, G
Rist, G
[J]. MACROMOLECULAR SYMPOSIA, 2004, 217 : 77 - 97
[9] Photocatalytic reductive cyclizations of enones: Divergent reactivity of photogenerated radical and radical anion intermediates
Du, Juana
Espelt, Laura Ruiz
Guzei, Ilia A.
Yoon, Tehshik P.
[J]. CHEMICAL SCIENCE, 2011, 2 (11) : 2115 - 2119
[10] Crossed Intermolecular [2+2] Cycloadditions of Acyclic Enones via Visible Light Photocatalysis
Du, Juana
Yoon, Tehshik P.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (41) : 14604 - +

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