Absolute Molecular Sieve Separation of Ethylene/Ethane Mixtures with Silver Zeolite A

被引：201

作者：

Aguado, Sonia ^{[1
]}

Bergeret, Gerard ^{[1
]}

Daniel, Cecile ^{[1
]}

Farrusseng, David ^{[1
]}

机构：

[1] Inst Rech Catalyse & Environm Lyon IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 36期

基金：

欧盟第七框架计划;

关键词：

ADSORPTIVE SEPARATION; PORE-SIZE; SELECTIVITY; CLUSTERS;

D O I：

10.1021/ja305663k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Absolute ethylene/ethane separation is achieved by ethane exclusion on silver-exchanged zeolite A adsorbent. This molecular sieving type separation is attributed to the pore size of the adsorbent, which falls between ethylene and ethane kinetic diameters.

引用

页码：14635 / 14637

页数：3

共 28 条

[1]

[Anonymous], 2001, USA Patent, Patent No. [US6200366, 6200366]

[2] Separation of ethylene/ethane mixtures by adsorption on small-pored titanosilicate molecular sieves [J].

Anson, A. ;

Lin, C. C. H. ;

Kuznicki, T. M. ;

Kuznicki, S. M. .

CHEMICAL ENGINEERING SCIENCE, 2010, 65 (02) :807-811

[3]

Carter J., 1967, US Patent, Patent No. 3355509

[4]

Cho S. H., 2001, US Patent, Patent No. [6315816, 6,315,816]

[5] Crystal structure of an ethylene sorption complex of fully dehydrated, fully oxidized, fully Ag+-exchanged zeolite X [J].

Choi, EY ;

Kim, SY ;

Kim, Y ;

Seff, K .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 62 (03) :201-210

[6] Pore-size engineering of zeolite a for the size/shape selective molecular separation [J].

Chudasama, CD ;

Sebastian, J ;

Jasra, RV .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (06) :1780-1786

[7]

Gascon J., 2009, WO Patent, Patent No. 2009104960

[8] THE NATURE OF THE CHARGED SILVER CLUSTERS IN DEHYDRATED ZEOLITES OF TYPE-A [J].

GELLENS, LR ;

MORTIER, WJ ;

SCHOONHEYDT, RA ;

UYTTERHOEVEN, JB .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (19) :2783-2788

[9] Performance of CaX Zeolite for Separation of C2H6, C2H4, and CH4 by Adsorption Process; Capacity, Selectivity, and Dynamic Adsorption Measurements [J].

Hosseinpour, S. ;

Fatemi, S. ;

Mortazavi, Y. ;

Gholamhoseini, M. ;

Ravanchi, M. Takht .

SEPARATION SCIENCE AND TECHNOLOGY, 2011, 46 (02) :349-355

[10]

Huang Y., 1980, J CATAL, V61, P476

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