An agar-based silver|silver chloride reference electrode for use in micro-electrochemistry

被引：149

作者：

Hassel, AW ^{[1
]}

Fushimi, K ^{[1
]}

Seo, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Lab Interfacial Electrochem, Kita Ku, Sapporo, Hokkaido 0608628, Japan

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 1999年 / 1卷 / 05期

基金：

日本学术振兴会;

关键词：

micro-reference electrodes; micro-electrochemistry; silver-silver chloride; scanning droplet cell;

D O I：

10.1016/S1388-2481(99)00035-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A miniaturised Ag \ AgCl reference electrode is described which can be easily set up. Its elechochemical behaviour was proven by micropolarisation curves, electrochemical impedance spectroscopy and potential transients. A saturated potassium chloride solution was used which was solidified by adding agar. The electrode is as small as 800 mu m in diameter and 5 mm in length, with further potential for down-sizing. A modified version includes an agar salt bridge in the same capillary. After an induction period of 6 h the potential becomes stable within 1 mV for more than 6 weeks. The electrode shows a slightly different reference potential, which is discussed in terms of the production process. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：180 / 183

页数：4

共 9 条

[1] A reference electrode for use in methanol solutions [J].