Mo/KIT-6, Fe/KIT-6 and Mo-Fe/KIT-6 as new types of heterogeneous catalysts for the conversion of MCP

被引：78

作者：

Boulaoued, Athmane ^{[1
,2
]}

Fechete, Ioana ^{[1
]}

Donnio, Bertrand ^{[3
]}

Bernard, Maxime ^{[2
]}

Turek, Philippe ^{[2
]}

Garin, Francois ^{[1
]}

机构：

[1] Univ Strasbourg, UMR CNRS 7515, Lab Mat Surfaces & Proc Catalyse, F-67087 Strasbourg 2, France

[2] Univ Strasbourg, UMR CNRS 7177, Lab POMAM, F-67008 Strasbourg, France

[3] Univ Strasbourg, UMR CNRS 7504, Inst Phys & Chim Mat Strasbourg, F-67034 Strasbourg 2, France

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2012年 / 155卷

关键词：

Methylcyclopentane; Fe catalysts; Mo catalysts; Fe-Mo catalysts; TEMPERATURE-PROGRAMMED REDUCTION; MESOPOROUS MOLECULAR-SIEVES; IRON-OXIDE NANOPARTICLES; SPECTROSCOPIC CHARACTERIZATION; MO CATALYSTS; FE; HYDROCARBONS; SURFACE; SILICA; METHYLCYCLOPENTANE;

D O I：

10.1016/j.micromeso.2012.01.028

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mo, Fe and Mo-Fe catalysts were prepared by the solid-solid method and systematically characterized by XRD, SEM, TEM, N-2 sorption, H-2-TPR, UV-vis, XPS and EPR physico-chemical techniques. The dispersion and the nature of the metal species depended strongly on the metal content. At low metal contents, isolated tetrahedrally coordinated metal entities and small nanoclusters were observed, whereas aggregates were formed at high metal loadings. The superior catalytic performance in the ring opening of MCP has been attributed to the highly dispersed isolated tetrahedral entities and highly dispersed small FeOx nanoclusters. The aggregates favor the cracking reactions. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：131 / 142

页数：12

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