Signaling molecularly imprinted polymers: Molecular recognition-based sensing materials

被引:46
作者
Takeuchi, T
Mukawa, T
Shinmori, H
机构
[1] Kobe Univ, Grad Sch Sci & Technol, Kobe, Hyogo 6578501, Japan
[2] JST, PRESTO, Kawaguchi 3320012, Japan
关键词
molecular imprinting; molecular recognition; signaling molecularly imprinted polymers; fluorescent monomers; metalloporphyrins;
D O I
10.1002/tcr.20052
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular imprinting is a template polymerization technique that can easily provide synthetic polymers capable of molecular recognition for given target molecules. In addition to their highly specific recognition ability, we are attempting to introduce signaling functions to molecularly imprinted polymers, enabling them to respond according to specific binding events. Some of our work regarding such signaling molecularly imprinted polymers is presented here, including molecularly imprinted polymers that induce spectral shifts of target compounds because of binding. Such compounds include hydrogen-bonding-based fluorescent imprinted polymers and metalloporphyrin-based signaling molecularly imprinted polymers. (c) 2005 The Japan Chemical journal Forum and Wiley Periodicals, Inc.
引用
收藏
页码:263 / 275
页数:13
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