Controlled Synthesis of the Henry Reaction Products: Nitroalcohol Versus Nitrostyrene by a Simple Change of Amino-Groups of Aminofunctionalized Nanoporous Catalysts

被引：31

作者：

Anan, Abhishek ^{[1
]}

Vathyam, Rajyalakshmi ^{[1
]}

Sharma, Krishna K. ^{[1
]}

Asefa, Tewodros ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

CATALYSIS LETTERS | 2008年 / 126卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

Henry reaction; Nitroaldol condensation; Amine-functionalized mesoporous materials; Nitrostyrene; Nitroalcohol;

D O I：

10.1007/s10562-008-9595-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either beta-nitrostyrene or beta-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

引用

收藏

页码：142 / 148

页数：7

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