Synthesis and crystal structure of Na4Sn3O8

被引：8

作者：

Iwasaki, M ^{[1
]}

Takizawa, H ^{[1
]}

Uheda, K ^{[1
]}

Endo, T ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 04期

关键词：

D O I：

10.1039/b107364h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new ternary Na-Sn-O compound, Na4Sn3O8, has been synthesized from a mixture of Na2CO3 and SnO2 by heating at 1270-1400 degreesC for 6-24 h in air using a powder bed. The crystal structure of Na4Sn3O8 has been refined by the Rietveld analysis of the powder X-ray diffraction data. Na4Sn3O8 crystallizes in the cubic system (a = 9.1815(2) Angstrom, Z = 4) with the space group of either P4(3)32 or P4(1)32. The unit cell contains twelve SnO6 and four NaO6 octahedra connecting by edge-sharing and additionally twelve sodium atoms distributed in octahedral holes.

引用

页码：1068 / 1070

页数：3

共 11 条

[1] CRYSTAL-STRUCTURE AND CONDUCTIVITY OF THE NEW SUPERIONIC CONDUCTOR AG4HF3S8 [J].

AMIEL, O ;

WADA, H .

JOURNAL OF SOLID STATE CHEMISTRY, 1995, 115 (01) :112-119

[2] CRYSTAL-STRUCTURE AND CONDUCTIVITY OF THE NEW SUPERIONIC CONDUCTORS AG4ZR3S8 AND AG3.8SN3S8 [J].

AMIEL, O ;

FRANKEL, DC ;

WADA, H .

JOURNAL OF SOLID STATE CHEMISTRY, 1995, 116 (02) :409-421

[3] Structure and Na+ ion conductivity inside double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M=Mn, Co and Ni) [J].

Dridi, N ;

Boukhari, A ;

Reau, JM ;

Holt, EM .

SOLID STATE IONICS, 1998, 107 (1-2) :25-30

[4] THE DIFFUSE REFLECTANCE SPECTRA OF MONO-CADMIUM AND DI-CADMIUM STANNATES [J].

GOLESTANIFARD, F ;

HOGARTH, CA ;

WATERS, DN .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1983, 2 (09) :505-510

[5] FAST NA+-ION TRANSPORT IN SKELETON STRUCTURES [J].

GOODENOUGH, JB ;

HONG, HYP ;

KAFALAS, JA .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :203-220

[6] THE STRUCTURE OF ION DEFICIENT SODIUM BETA-''-ALUMINA [J].

HAYCOCK, PW ;

HAYES, W ;

WARD, RCC ;

SALTER, CJ ;

HARVERSON, RJ .

SOLID STATE IONICS, 1995, 80 (1-2) :53-58

[7] CRYSTAL-STRUCTURES AND CRYSTAL-CHEMISTRY IN SYSTEM NA1+XZR2SIXP3-XO12 [J].

HONG, HYP .

MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :173-182

[8] A Rietveld-analysis program RIETAN-98 and its applications to zeolites [J].

Izumi, F ;

Ikeda, T .

EUROPEAN POWDER DIFFRACTION, PTS 1 AND 2, 2000, 321-3 :198-203

[9] Spray pyrolysis preparation and humidity sensing characteristics of spinel zinc stannate thin films [J].

Stambolova, I ;

Konstantinov, K ;

Kovacheva, D ;

Peshev, P ;

Donchev, T .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 128 (02) :305-309

[10] Formation and structure of Ti-Zn-oxides [J].

Steinike, U ;

Wallis, B .

CRYSTAL RESEARCH AND TECHNOLOGY, 1997, 32 (01) :187-193

← 1 2 →