Kinetic evaluation of the direct synthesis of ethers from alcohols over sulfonated resin catalysts

被引：13

作者：

Lietti, L

Sun, Q

Herman, RG

Klier, K

机构：

[1] Department of Chemistry, Zettlemoyer Ctr. for Surface Studies, Lehigh University, Bethlehem

[2] Dipto. Chim. Industriale ed Ing. C., Politecnico di Milano, Milano

来源：

CATALYSIS TODAY | 1996年 / 27卷 / 1-2期

关键词：

sulfonated resin catalysts; ethers; direct synthesis from alcohols; kinetics;

D O I：

10.1016/0920-5861(95)00183-2

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The acidic Amberlyst-35 sulfonated resin effectively catalyzes the coupling of methanol + isobutanol and ethanol + isobutanol mixtures in the gas-phase to give methyl isobutyl ether and ethyl isobutyl ether, respectively. The reaction occurs via a S(N)2 reaction pathway involving two adsorbed alcohol molecules and is successfully described by a simple Langmuir-Hinshelwood kinetics.

引用

页码：151 / 158

页数：8

共 7 条

[1]

ANCILLOTTI F, 1977, J CATAL, V46, P49, DOI 10.1016/0021-9517(77)90134-8

[2] LANGMUIR-HINSHELWOOD KINETICS OF DEHYDRATION OF METHANOL CATALYZED BY CATION EXCHANGE RESIN [J].