Novel spin-polarized TTF donors affording ground state triplet cation diradicals

被引：55

作者：

Nakazaki, J ^{[1
]}

Matsushita, MM ^{[1
]}

Izuoka, A ^{[1
]}

Sugawara, T ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Tokyo 1538902, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 27期

关键词：

electron donors; electron spin resonance; radicals and radical reactions; sulfur heterocycles;

D O I：

10.1016/S0040-4039(99)00925-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The concept or "spin-polarized" donor was successfully extended to TTF-based donor radicals. A series of TTF derivatives carrying a phenyl nitronyl nitroxide group were prepared, and they turned out to afford ground state triplet cation diradicals through one-electron oxidation. Such "spin-polarized" TTF donors are expected to become building blocks for organic conducting ferromagnets. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5027 / 5030

页数：4

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