Voltammetric method for distinguishing between electrochemical reactions involving solid or dissolved analytes within carbon paste electrodes

被引：6

作者：

Bachiller, PE ^{[1
]}

Garcia, MLT ^{[1
]}

Barbado, MDV ^{[1
]}

Batanero, PS ^{[1
]}

机构：

[1] UNIV VALLADOLID,FAC SCI,ELECTROANALYT CHEM LAB,DEPT ANALYT CHEM,VALLADOLID,SPAIN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 424卷 / 1-2期

关键词：

carbon paste electrodes; voltammetry; analytes; electrochemical reactions;

D O I：

10.1016/S0022-0728(96)04905-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method for distinguishing between solid and solution phase reactions has been developed. The method is based on comparison of data obtained from voltammograms of the solid and those obtained with the binder containing an extract of the solid.

引用

页码：217 / 220

页数：4

共 17 条

[1]

BACHILLER PE, 1994, J ELECTROANAL CHEM, V367, P99

[2] CARBON PASTE ELECTRODES FOR STUDYING SOLID STANNIC OXIDE ELECTROCHEMISTRY [J].

EGUREN, M ;

TASCON, ML ;

VAZQUEZ, MD ;

BATANERO, PS .

ELECTROCHIMICA ACTA, 1988, 33 (07) :1009-1011

[3]

EGUREN M, 1987, QUIM ANAL, V6, P295

[4] ELECTROCHEMICAL REACTIVITY OF SOME VANADIUM-OXIDES IN 1M-HCL MEDIA [J].

ELOUADSERI, MM ;

VITTORI, O ;

DURAND, B .

ELECTROCHIMICA ACTA, 1986, 31 (10) :1335-1339

[5]

ENCINAS P, 1994, J ELECTROANAL CHEM, V371, P1561

[6] ELECTROCHEMICAL-BEHAVIOR OF COPPER, LEAD, AND BISMUTH SOLID COMPOUNDS AND THEIR TERNARY MIXTURES AT SOLID-STATE AT A CARBON-PASTE ELECTRODE WITH ELECTROLYTIC BINDER - APPLICATION TO THE STUDY OF THE HIGH TRANSITION-TEMPERATURE SUPERCONDUCTOR BI-0.7-CENTER-DOT-PB-0.3-CENTER-DOT SR-CENTER-DOT-CA-CENTER-DOT-CU-1.8-CENTER-DOT-O-X [J].

ESPINOSA, AM ;

TASCON, ML ;

ENCINAS, P ;

VAZQUEZ, MD ;

SANCHEZBATANERO, P .

ELECTROCHIMICA ACTA, 1995, 40 (11) :1623-1632

[7]

GAVASSO R, 1979, J ELECTROANAL CHEM, V102, P249

[8]

LAMACHE M, 1977, J ELECTROANAL CHEM, V79, P359, DOI 10.1016/0368-1874(77)80232-3

[9] THEORY OF I-T CURVES AT CONSTANT POTENTIAL IN CASE OF A SOLID WHOSE REDUCTION OR OXIDATION IS PRECEDED BY ITS DISSOLUTION [J].

LAVIRON, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1978, 90 (01) :33-47

[10]

LECUIRE JM, 1973, ANALUSIS, V2, P489

← 1 2 →