Carboxylated butadiene-styrene rubber/halloysite nanotube nanocomposites: Interfacial interaction and performance

被引：208

作者：

Du, Mingliang ^{[1
]}

Guo, Baochun ^{[1
]}

Lei, Yanda ^{[1
]}

Liu, Mingxian ^{[1
]}

Jia, Demin ^{[1
]}

机构：

[1] S China Univ Technol, Dept Polymer Mat & Engn, Guangzhou 510640, Peoples R China

来源：

POLYMER | 2008年 / 49卷 / 22期

基金：

中国国家自然科学基金;

关键词：

Carboxylated styrene-butadiene rubber; Halloysite nanotubes; Hydrogen bonding;

D O I：

10.1016/j.polymer.2008.08.042

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A co-coagulation process was utilized to prepare carboxylated butadiene-styrene rubber (xSBR)/halloysite nanotube (HNT) nanocomposites. The interfacial interaction, morphology, and the mechanical performance of the nanocomposites were investigated. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS) results indicate the formation of hydrogen bonding between xSBR and HNTs. Lower content of HNTs tends to delay the vulcanization of xSBR/HNT compounds, while higher HNT loading promotes the vulcanization. It is shown that HNTs are dispersed individually and uniformly in the matrix with strong interfacial bonding. The mechanical properties, especially the modulus and hardness, are significantly increased by the inclusion of HNTs. The significant reinforcing effects of HNTs are correlated to the co-coagulation process and strong interfacial interactions via hydrogen bonding. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：4871 / 4876

页数：6

共 46 条

[1] Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].

Alexandre, Michael ;

Dubois, Philippe .

Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63

[2] Strongly thixotropic viscosity behavior of dimethylsulfoxide solution of polyrotaxane comprising α-cyclodextrin and low molecular weight poly(ethylene glycol) [J].

Araki, Jun ;

Ito, Kohzo .

POLYMER, 2007, 48 (24) :7139-7144

[3] Organo-montmorillonite as substitute of carbon black in natural rubber compounds [J].

Arroyo, M ;

López-Manchado, MA ;

Herrero, B .

POLYMER, 2003, 44 (08) :2447-2453

[4] Nylon 6 nanocomposites by melt compounding [J].

Cho, JW ;

Paul, DR .

POLYMER, 2001, 42 (03) :1083-1094

[5] Vulcanization kinetics of nitrile rubber/layered clay nanocomposites [J].

Choi, D ;

Kader, MA ;

Cho, BH ;

Huh, Y ;

Nah, C .

JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (04) :1688-1696

[6] Properties of natural rubber composites reinforced with silica or carbon black: influence of cure accelerator content and filler dispersion [J].

Choi, SS ;

Nah, C ;

Byung-Wook, J .

POLYMER INTERNATIONAL, 2003, 52 (08) :1382-1389

[7] Thermal analysis of complex relaxation processes in poly(desaminotyrosyl-tyrosine arylates) [J].

Collins, George ;

Yoo, Seung-uk ;

Recber, Ali ;

Jaffe, Michael .

POLYMER, 2007, 48 (04) :975-988

[8] Probing the urea hard domain connectivity in segmented, non-chain extended polyureas using hydrogen-bond screening agents [J].

Das, Sudipto ;

Yilgor, Iskender ;

Yilgor, Emel ;

Wilkes, Garth L. .

POLYMER, 2008, 49 (01) :174-179

[9] Preparation and characterization of polypropylene grafted halloysite and their compatibility effect to polypropylene/halloysite composite [J].

Du, Mingliang ;

Guo, Baochun ;

Liu, Mingxian ;

Jia, Demin .

POLYMER JOURNAL, 2006, 38 (11) :1198-1204

[10] Rubber nanocomposites:: Morphology and mechanical properties of BR and SBR vulcanizates reinforced by organophilic layered silicates [J].

Ganter, M ;

Gronski, W ;

Reichert, P ;

Mülhaupt, R .

RUBBER CHEMISTRY AND TECHNOLOGY, 2001, 74 (02) :221-235

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