Oximate-bridged trinuclear Dy-Cu-Dy complex behaving as a single-molecule magnet and its mechanistic investigation

被引：323

作者：

Mori, F

Nyui, T

Ishida, T ^{[1
]}

Nogami, T

Choi, KY

Nojiri, H

机构：

[1] Univ Electrocommun, Dept Appl Phys & Chem, Chofu, Tokyo 1828585, Japan

[2] Univ Electrocommun, Course Coherent Opt Sci, Chofu, Tokyo 1828585, Japan

[3] Japan Sci & Technol Agcy, CREST, Sendai, Miyagi 9808577, Japan

[4] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 05期

关键词：

D O I：

10.1021/ja057183f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lanthanide ions are supposed to be promising candidates for the elements of single-molecule magnets (SMMs) because of the large magnetic momentum and anisotropy. We have established the [Dy2Cu] complex as a new SMM. A plausible mechanism for quantum tunneling of magnetization is proposed for the first time among the 4f-3d heterometallic SMMs. The magnetic coupling parameter between Dy and Cu ions was well-defined as -0.155 K. Copyright © 2006 American Chemical Society.

引用

页码：1440 / 1441

页数：2

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