Synthesis and crystal structure of new sulfate-bridged coordination polymer, {(4,4′-bpyH2)[Fe3(4,4′-bpy)3(SO4)4(H2O)6]•10H2O}n (4,4′-bpy=4,4′-bipyridine).: Three-dimensional network with microporous channels

被引：16

作者：

Noro, S

Kondo, M

Kitagawa, S

Ishii, T

Matsuzaka, H

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 6068501, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 08期

关键词：

D O I：

10.1246/cl.1999.727

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new sulfate-bridged coordination polymer, {(4,4'-bpyH(2))[Fe-3(4,4'-bpy)(3)(SO4)(4)(H2O)(6)]. 10H(2)O}(n), was synthesized and crystallographically characterized. This complex shows a novel three-dimensional (3-D) log-cabin type structure constructed from one-dimensional (1-D) [Fe(4,4'-bpy)(H2O)(2)](n) cationic chain, free protonated 4,4'-bpy, and sulfate dianion. This structure shows channel-like cavities with dimensions of about 3 Angstrom x 4 Angstrom.

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页码：727 / 728

页数：2

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