The first mononuclear triazatrimethylenemethane metal complex, [Pt{NPhC(NPh)NPh}(cod)] (cod=cycloocta-1,5-diene)

被引：36

作者：

Dinger, MB ^{[1
]}

Henderson, W ^{[1
]}

机构：

[1] UNIV WAIKATO,DEPT CHEM,HAMILTON,NEW ZEALAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a mononuclear complex containing the triazatrimethylenemethane ligand is prepared by the silver(I) oxide-mediated reaction of [PtCl2(cod)] with N,N',N '' riphenylguanidine; the single-crystal X-ray structure shows that the ligand bonds in an eta(2) fashion, forming an essentially planar four-membered PtNCN metallacycle.

引用

收藏

页码：211 / 212

页数：2

相关论文

共 43 条

[1] MASS-SPECTRA AND THE MACINTOSH - ISOTOPE PATTERN CALCULATOR - A PROGRAM TO CALCULATE ISOTOPIC-RATIOS FOR MOLECULAR FRAGMENTS [J].

ARNOLD, LJ .

JOURNAL OF CHEMICAL EDUCATION, 1992, 69 (10) :811-811

[2] THE FIRST TRIAZATRIMETHYLENEMETHANE DIANION - CRYSTAL-STRUCTURE OF DILITHIO-TRIPHENYLGUANIDINE LI-2[C(NPH)(3)] AS ITS TETRAHYDROFURAN SOLVATE [J].

BAILEY, PJ ;

BLAKE, AJ ;

KRYSZCZUK, M ;

PARSONS, S ;

REED, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1647-1648

[3] REACTIONS OF TOLUENE-P-SULFONYL AZIDE AND ISOCYANATE WITH LOW VALENT TRANSITION-METAL COMPLEXES [J].

BECK, W ;

RIEBER, W ;

CENINI, S ;

PORTA, F ;

LAMONICA, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (03) :298-304

[4] TRANSITION-METAL-MEDIATED REACTIONS OF ORGANIC ISOCYANATES [J].

BRAUNSTEIN, P ;

NOBEL, D .

CHEMICAL REVIEWS, 1989, 89 (08) :1927-1945

[5] SYNTHESIS AND STUDIES OF DEHYDRO-NN'N''-TRIALKYLGUANIDINOHEXACARBONYLDI-IRON(0) [J].

BREMER, NJ ;

CUTCLIFF.AB ;

FARONA, MF ;

KOFRON, WG .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (21) :3264-&

[6]

CENINI S, 1976, INORG CHIM ACTA REV, V18, P279

[7] THE 1ST PLATINUM ETA-3-AZATRIMETHYLENEMETHANES AND PLATINAPYRAZOLINES FORMED FROM REGIOSELECTIVE ADDITION OF AMINE OR HYDRAZINE TO A ALPHA-ALLENYL COMPLEX OF PLATINUM(II) [J].

CHEN, JT ;

HUANG, TM ;

CHENG, MC ;

LIN, YC ;

WANG, Y .

ORGANOMETALLICS, 1992, 11 (05) :1761-1763

[8]

CHIO N, 1992, ORGANOMETALLICS, V11, P1506

[9] CHEMISTRY OF METALLACYCLOBUTANONES .4. THE SYNTHESIS OF 1,3-DIPHENYL-SUBSTITUTED OXODIMETHYLENEMETHANE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II) VIA THE DIANION [PHCHC(O)CHPH]2-, AND THE X-RAY CRYSTAL-STRUCTURE OF [PT(ETA-3-CHPHC(O)CHPH)(ASPH3)2].2CH2CL2 [J].

CHIU, KW ;

HENDERSON, W ;

KEMMITT, RDW ;

PROUSE, LJS ;

RUSSELL, DR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02) :427-432

[10] STRUCTURAL STUDIES OF ORGANONITROGEN COMPOUNDS OF TRANSITION ELEMENTS .I. CRYSTAL AND MOLECULAR STRUCTURE OF MU-DIMETHYLUREYLENE-BIS(TRICARBONYLIRON [CH3N)2CO]FE2(CO)6 [J].

DOEDENS, RJ .

INORGANIC CHEMISTRY, 1968, 7 (11) :2323-&

← 1 2 3 4 5 →