New 3-deoxyanthocyanidins from leaves of Arrabidaea chica

被引:54
作者
Devia, B
Llabres, G
Wouters, J
Dupont, L
Escribano-Bailon, MT
de Pascual-Teresa, S
Angenot, L
Tits, M
机构
[1] Univ Liege, CHU Sart Tilman, Inst Pharm, Lab Pharmacognosy, B-4000 Cointe Ougree, Belgium
[2] Univ Liege, Inst Phys B5, B-4000 Liege, Belgium
[3] Royal Inst Cultural Heritage, B-1000 Brussels, Belgium
[4] Univ Salamanca, Fac Farm, Lab Nutr & Bromatol, E-37007 Salamanca, Spain
关键词
high speed countercurrent chromatography; HPLC-MS; NMR; X-ray; carajurin; 3-deoxyanthocyanidin; Arrabidaea chica;
D O I
10.1002/pca.632
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Two new 3-deoxyanthocyanidins, 6,7,3',4'-tetrahydroxy-5-methoxyflavylium and 6,7,4'-trihydroxy-5-methoxyflavylium, and the pigment carajurin, which has been previously identified, were isolated from dried leaves of Arrabidaea chica, a creeper native to the American tropics. The structures of the components were elucidated by H-1- and C-13-NMR spectroscopy and HPLC-MS, including X-ray crystallographic analysis for carajurin. Copyright (C) 2002 John Wiley Sons, Ltd.
引用
收藏
页码:114 / 120
页数:7
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