Crystalline alternating sequences identified in ethylene-co-norbornene polymers produced by the (η5-C2B9H11)Zr(NEt2)2(NHEt2)-AliBu3 catalyst

被引：42

作者：

Altamura, P ^{[1
]}

Grassi, A ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, Italy

来源：

MACROMOLECULES | 2001年 / 34卷 / 26期

关键词：

D O I：

10.1021/ma011138k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In order to gain further insight into dicarbollide-catalyzed ethylene-norbornene polymerization, the behavior of the (η5-C2B9H11)- Zr(NRt2)2(NHEt2)-TIBA catalyst was studied and preliminary compared with that of Me2Si(3-tBuCp)(adamantylamido)- ZrCl2/MAO (2) and (η5-C5Me5)- ZrCl3-MAO (3). Several ethylene-norbornene copolymerizations were carried out over a wide range of monomer compositions. The resulting polymer products were analyzed by 13C NMR spectroscopy to gain information about the copolymer microstructure.

引用

页码：9197 / 9200

页数：4

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