Di-μ-chloro-bis{chloro[(4a,5,6,7,8,8a-η6)-1,2,3,4-tetrahydronaphthalene]ruthenium(II)}

被引:13
作者
Bown, M [1 ]
Bennett, MA [1 ]
机构
[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia
关键词
D O I
10.1107/S0108270199002589
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, [{RuCl(eta(6)-C10H12)}(2)(mu-Cl)(2)] or [Ru2Cl4(C10H12)(2)], has the expected edge-sharing bi-octahedral geometry, in which two crystallographically related [(4a,5,6,7,8,8a-eta(6))-1,2,3,4-tetrahydronaphthalene]RuCl2 moieties are asymmetrically bridged by two symmetry-related Cl atoms, with Ru-mu-Cl bond lengths of 2.438(1) and 2.440(1)Angstrom, and a terminal Ru-Cl bond length of 2.397(1)Angstrom.
引用
收藏
页码:852 / 854
页数:3
相关论文
共 15 条
[1]   Thermally induced endo to exo isomerization in the o-xylylene complexes of zerovalent ruthenium and osmium, M(η6-C6Me6){η4-o-(CH2)2C6Me4} (M = Ru, Os) [J].
Bennett, MA ;
Bown, M ;
Byrnes, MJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (01) :139-144
[2]   DOUBLE DEPROTONATION OF RUTHENIUM(II) CATIONS CONTAINING 1,2-DIMETHYL-SUBSTITUTED ETA-6-ARENES - PROTONATION OF THE RESULTING EXO-COORDINATED (ORTHO-XYLYLENE)RUTHENIUM(0) COMPLEXES AND X-RAY CRYSTAL-STRUCTURES OF THE AGOSTIC (ETA-3-PENTAMETHYLBENZYL)RUTHENIUM(II) COMPLEXES [RU(,ETA-3-(HCH2)(CH2)C6ME4)((Z)-PH2PCH=CHPPH2)(PME2PH)]PF6 AND [RU(ETA-3-(HCH2)(CH2)C6ME4)(PME2PH)3]PF6 [J].
BENNETT, MA ;
GOH, LY ;
MCMAHON, IJ ;
MITCHELL, TRB ;
ROBERTSON, GB ;
TURNEY, TW ;
WICKRAMASINGHE, WA .
ORGANOMETALLICS, 1992, 11 (09) :3069-3085
[3]   Dissociative and nondissociative pathways in the endo to exo isomerization of tetramethyl-o-xylylene complexes of ruthenium and osmium, ML3{η4-o-C6Me4(CH2)2} (M = Ru, L = PMe3; M = Os, L = PMe3, PMe2Ph).: Formation of hexamethylbenzene-1,2-diyl complexes by ligand addition to the exo-osmium complexes [J].
Bennett, MA ;
Bown, M ;
Hockless, DCR ;
McGrady, JE ;
Schranz, HW ;
Stranger, R ;
Willis, AC .
ORGANOMETALLICS, 1998, 17 (17) :3784-3797
[4]   SYNTHESIS AND STRUCTURE OF ENDO-COORDINATED O-XYLYLENE COMPLEXES OF ZEROVALENT RUTHENIUM AND OSMIUM, M(ETA(4)-O-(CH2)(2)C6H4)(PME(2)PH)(3) (M=RU, OS), AND OF A TRICARBONYLIRON ADDUCT OF THE RUTHENIUM COMPLEX [J].
BENNETT, MA ;
BOWN, M ;
GOH, LY ;
HOCKLESS, DCR ;
MITCHELL, TRB .
ORGANOMETALLICS, 1995, 14 (02) :1000-1007
[5]  
BEURSKENS PT, 1992, DIRDIF PROGRAM SYSTE
[6]   SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NAPHTHALENE COMPLEX OF RUTHENIUM, [RU(ETA-6-C10H8)(ETA-4-CYCLO-OCTA-1,5-DIENE)] [J].
CROCKER, M ;
GREEN, M ;
HOWARD, JAK ;
NORMAN, NC ;
THOMAS, DM .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (07) :2299-2301
[7]  
Gupta HK, 1997, ORGANOMETALLICS, V16, P4355
[8]   REACTIVITY OF [(1,2,3,4-TETRAHYDRONAPHTHALENE)MN(CO)(3)]PF6 - MOLECULAR-STRUCTURE OF [(1,2,3,4-TETRAHYDRONAPHTHALENE)MN(CO)(2)(C(O)ME)] [J].
LEE, TY ;
LEE, SS ;
CHUNG, YK ;
LEE, SW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 486 (1-2) :141-145
[9]   THE STRUCTURE OF DI-MU-CHLORO-BIS[CHLORO(ETA-6-HEXAMETHYLBENZENE)RUTHENIUM(II)]-CHLOROFORM (1/2) [J].
MCCORMICK, FB ;
GLEASON, WB .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :603-605
[10]   Linkage isomerism in complexes of o-xylylene: Density functional study of the structure and bonding in endo- and exo-Ru(PH3)(3)(o-xylylene) [J].
McGrady, JE ;
Stranger, R ;
Bown, M ;
Bennett, MA .
ORGANOMETALLICS, 1996, 15 (14) :3109-3114