High efficiency CH3NH3PbI(3-x)Clx, perovskite solar cells with poly(3-hexylthiophene) hole transport layer

被引:145
作者
Di Giacomo, Francesco [1 ]
Razza, Stefano [1 ]
Matteocci, Fabio [1 ]
D'Epifanio, Alessandra [2 ]
Licoccia, Silvia [2 ]
Brown, Thomas M. [1 ]
Di Carlo, Aldo [1 ]
机构
[1] Univ Roma Tor Vergata, Dept Elect Engn, CHOSE, I-00133 Rome, Italy
[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy
关键词
Perovskite solar cell; Doped P3HT; Thin film photovoltaics; Organometal Halide Perovskite; LOW-COST; PERFORMANCE;
D O I
10.1016/j.jpowsour.2013.11.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We fabricate perovskite based solar cells using CH3NH3PbI3-xClx with different hole-transporting materials. The most used 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)9,9'-spirobifluorene (Spiro-OMeTAD) has been compared to the poly(3-hexylthiophene-2,5-diyl) (P3HT). By tuning the energy level of P3HT and optimizing the device's fabrication, we reached 9.3% of power conversion efficiency, which is the highest reported efficiency for a solar cell using P3HT. This result shows that P3HT can be a suitable low cost hole transport material for efficient perovskite based solar cells. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:152 / 156
页数:5
相关论文
共 32 条
[1]  
Abrusci A., 2013, NANO LETT
[2]   High-Performance Perovskite-Polymer Hybrid Solar Cells via Electronic Coupling with Fullerene Monolayers [J].
Abrusci, Agnese ;
Stranks, Samuel D. ;
Docampo, Pablo ;
Yip, Hin-Lap ;
Jen, Alex K-Y. ;
Snaith, Henry J. .
NANO LETTERS, 2013, 13 (07) :3124-3128
[3]   Review of stability for advanced dye solar cells [J].
Asghar, Muhammad Imran ;
Miettunen, Kati ;
Halme, Janne ;
Vahermaa, Paula ;
Toivola, Minna ;
Aitola, Kerttu ;
Lund, Peter .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (04) :418-426
[4]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[5]   Effect of Different Hole Transport Materials on Recombination in CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells [J].
Bi, Dongqin ;
Yang, Lei ;
Boschloo, Gerrit ;
Hagfeldt, Anders ;
Johansson, Erik M. J. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (09) :1532-1536
[6]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[7]   Efficient panchromatic inorganic-organic heterojunction solar cells with consecutive charge transport tunnels in hole transport material [J].
Chen, Haiwei ;
Pan, Xu ;
Liu, Weiqing ;
Cai, Molang ;
Kou, Dongxing ;
Huo, Zhipeng ;
Fang, Xiaqin ;
Dai, Songyuan .
CHEMICAL COMMUNICATIONS, 2013, 49 (66) :7277-7279
[8]   Thin-film photovoltaics [J].
Dherea, NG ;
Dhere, RG .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2005, 23 (04) :1208-1214
[9]   Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance [J].
Ding, I-Kang ;
Tetreault, Nicolas ;
Brillet, Jeremie ;
Hardin, Brian E. ;
Smith, Eva H. ;
Rosenthal, Samuel J. ;
Sauvage, Frederic ;
Graetzel, Michael ;
McGehee, Michael D. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (15) :2431-2436
[10]   Thin film solar modules: The low cost, high throughput and versatile alternative to Si wafers [J].
Hegedus, S. .
PROGRESS IN PHOTOVOLTAICS, 2006, 14 (05) :393-411