Mounting Freestanding Molecular Functions onto Surfaces: The Platform Approach

被引：148

作者：

Baisch, Belinda ^{[1
]}

Raffa, Diego ^{[1
]}

Jung, Ulrich ^{[1
]}

Magnussen, Olaf M. ^{[1
]}

Nicolas, Cyril ^{[2
]}

Lacour, Jerome ^{[2
]}

Kubitschke, Jens ^{[3
]}

Herges, Rainer ^{[3
]}

机构：

[1] Univ Kiel, Inst Expt & Appl Phys, D-24098 Kiel, Germany

[2] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

[3] Univ Kiel, Otto Diels Inst Organ Chem, D-24098 Kiel, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 02期

关键词：

SELF-ASSEMBLED MONOLAYERS; EN-ROUTE; TRIPOD; FRAMEWORK; GOLD;

D O I：

10.1021/ja807923f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A modular system has been developed to mount molecules upright onto metal surfaces in a well controlled geometry. The approach is based on a reactive platform (triazatriangulenium salt) with an electrophilic center. Functional molecules are attached via C-C bond formation. The distance from the surface can be varied by a spacer, and the distance of the functional units from each other by the size of the platform. Self-assembly of the parent triazaangulenium salt as welt as the functionalized platforms on Au(111) surfaces results in stable, hexagonally ordered adlayers.

引用

页码：442 / +

页数：3

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