Preparation and Evaluation of Carboxymethylated Lignin as Dispersant for Aqueous Graphite Suspension Using Turbiscan Lab Analyzer

被引:52
作者
Gan, Linhuo [1 ,2 ,3 ]
Zhou, Mingsong [1 ,2 ]
Yang, Dongjie [1 ,2 ]
Qiu, Xueqing [1 ,2 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
[2] S China Univ Technol, Guangdong Prov Lab Green Chem Technol, Guangzhou 510641, Guangdong, Peoples R China
[3] Huaqiao Univ, Coll Chem Engn, Xiamen, Peoples R China
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
Carboxymethylation; dispersion stability; graphite suspension; wheat straw alkali lignin; WHEAT-STRAW; FLOCCULATION; PERFORMANCE; OXIDATION; AGENT;
D O I
10.1080/01932691.2012.686248
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carboxymethylated lignin (CML) was prepared from wheat straw alkali lignin (WAL) via carboxymethylation modification. The characterizations using FTIR, C-13 NMR, and (HC)-H-1-C-13 HSQC NMR suggest that carboxyl groups are introduced into WAL structure successfully and there are two different active sites substituted by carboxymethyl groups. Moreover, the dispersion efficiency of CML was evaluated using the Turbiscan Lab analyzer. Effects of CML dosage and suspension pH on the dispersion stability of aqueous graphite suspension were investigated. The result shows that the dispersion stability of aqueous graphite suspension prepared with CML of 1.0% dosage at suspension pH 6.7 is obviously improved. <graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="ldis_a_686248_o_uf0001.gif"></graphic
引用
收藏
页码:644 / 650
页数:7
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