Synthesis of polycyclic hydrocarbons by palladium-catalyzed cross-coupling reactions of vinylic bromides with diphenylacetylene

被引:22
作者
Dyker, G
Siemsen, P
Sostmann, S
Wiegand, A
Dix, I
Jones, PG
机构
[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,D-38106 BRAUNSCHWEIG,GERMANY
[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN CHEM & ANALYT CHEM,D-38106 BRAUNSCHWEIG,GERMANY
来源
CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 02期
关键词
polycycles; hydrocarbons; palladium catalysis; domino processes; cross coupling; homogeneous catalysis;
D O I
10.1002/cber.19971300220
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Vinylic bromides of type 1 undergo cross-coupling reactions with diphenylacetylene (5) leading to various polycyclic hydrocarbons. The ratio of the 1:1 to the 1:2 products can readily be controlled by varying the reaction conditions.
引用
收藏
页码:261 / 265
页数:5
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