Synthesis, structure, and properties of a dimeric chromium(II) pyrazolato complex with a long chromium-chromium distance. Maintenance of a dimeric structure in solution and interconversion between dimeric and monomeric structures

被引：14

作者：

El-Kadri, Oussama M. ^{[1
]}

Heeg, Mary Jane ^{[1
]}

Winter, Charles H. ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 14期

关键词：

D O I：

10.1021/ic060749w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, solid-state structure, and solution structure of Cr-2(tBu(2)pz)(4) are described. This complex is obtained by sublimation of the monomeric species Cr(tBu(2)pz)(2)(4-tBupy)(2) and contains long chromium-chromium distances that are enforced by the divergent nature of the pyrazolato ligands.

引用

页码：5278 / 5280

页数：3

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