A simple unimolecular multiplexer/demultiplexer

被引:120
作者
Amelia, Matteo [1 ]
Baroncini, Massimo [1 ]
Credi, Alberto [1 ]
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
关键词
binary logic; luminescence; molecular devices; photochemistry; quinolines;
D O I
10.1002/anie.200802018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simple but effective! 8-Methoxyquinoline, an unsophisticated fluorophore, displays both 2:1 multiplexer and 1:2 demultiplexer digital functions (see picture). Protonation of the fluorophore results in completely different optical spectral profiles and multiplexing/demultiplexing behavior is obtained by exploiting the proton-driven reversible modulation of two complementary absorption and fluorescence signals. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6240 / 6243
页数:4
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