A new method for the generation and capture of iminyl radicals

被引：54

作者：

Boivin, J

Schiano, AM

Zard, SZ ^{[1
]}

Zhang, HW

机构：

[1] Ecole Polytech, CNRS, Organ Synth Lab, F-91128 Palaiseau, France

[2] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(99)00720-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iminyl radicals can be generated from ketoxime eaters and captured by an internal olefin; the sequence may be terminated in a variety of ways depending on the nature of the ensuing carbon radical and the added external trap. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4531 / 4534

页数：4

共 27 条

[1] REDUCTIVE FORMYLATION OF OXIMES - AN APPROACH TO THE SYNTHESIS OF VINYL ISONITRILES
BARTON, DHR
BOWLES, T
HUSINEC, S
FORBES, JE
LLOBERA, A
PORTER, AEA
ZARD, SZ
[J]. TETRAHEDRON LETTERS, 1988, 29 (27) : 3343 - 3346
[2] A FURTHER SYNTHESIS OF THE CORTICOSTEROID SIDE-CHAIN STARTING WITH A SUITABLE 17-KETONE
BARTON, DHR
ZARD, SZ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (10): : 2191 - 2192
[3] NOVEL ANALGESICS AND MOLECULAR REARRANGEMENTS IN MORPHINE-THEBAINE GROUP .I. KETONES DERIVED FROM 6,14-ENDO-ETHENOTETRAHYDROTHEBAINE
BENTLEY, KW
HARDY, DG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (13) : 3267 - &
[4] RECENT PROGRESS IN THE USE OF SULFONYL RADICALS IN ORGANIC-SYNTHESIS - A REVIEW
BERTRAND, MP
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1994, 26 (03) : 257 - 290
[5] SIMPLE SYNTHESIS OF ENAMIDES FROM KETOXIMES
BOAR, RB
MCGHIE, JF
ROBINSON, M
BARTON, DHR
HORWELL, DC
STICK, RV
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (13): : 1237 - 1241
[6] NEW AND CONVENIENT SYNTHESIS OF "17ALPHA,21-DIACETOXY-20-OXOPREGNANE SIDE-CHAIN
BOAR, RB
MCGHIE, JF
ROBINSON, M
BARTON, DHR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (13): : 1242 - 1244
[7] A NOVEL AND PRACTICAL ACCESS TO 13-EPI-17-KETOSTEROIDS
BOIVIN, J
SCHIANO, AM
ZARD, SZ
[J]. TETRAHEDRON LETTERS, 1992, 33 (51) : 7849 - 7852
[8] IMINYL RADICALS BY STANNANE MEDIATED CLEAVAGE OF OXIME ESTERS
BOIVIN, J
SCHIANO, AM
ZARD, SZ
[J]. TETRAHEDRON LETTERS, 1994, 35 (02) : 249 - 252
[9] IMINYL, AMIDYL, AND CARBAMYL RADICALS FROM O-BENZOYL OXIMES AND O-BENZOYL HYDROXAMIC ACID-DERIVATIVES
BOIVIN, J
CALLIERDUBLANCHET, AC
QUICLETSIRE, B
SCHIANO, AM
ZARD, SZ
[J]. TETRAHEDRON, 1995, 51 (23) : 6517 - 6528
[10] REACTION OF OXIME O-ACETATES WITH CHROMOUS ACETATE - A METHOD FOR CONVERSION OF KETOXIMES TO KETONES UNDER MILD CONDITIONS
COREY, EJ
RICHMAN, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (17) : 5276 - &

← 1 2 3 →