Formation of novel P-functionalized ligands by insertion reactions into the Zr-P bond of Cp degrees(2)ZrCl(PHCy) (Cp degrees=eta(5)-C5EtMe4, Cy equals cyclohexyl)

被引：21

作者：

Segerer, U ^{[1
]}

HeyHawkins, E ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

POLYHEDRON | 1997年 / 16卷 / 15期

关键词：

zirconocene monophosphanido complex; insertion reaction; phosphinodithioformato ligand; N-phenylthiophosphinoamidato ligand;

D O I：

10.1016/S0277-5387(97)00001-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cp-2 degrees ZrCl2 (Cp degrees = eta(5)-C5EtMe4) reacts with LiPHCy (Cy = cyclohexyl) with the formation of Cp-2 degrees ZrCl(PHCy) (1). Compound 1 undergoes insertion of CS2 or PhNCS into the Zr-P bond, yielding Cp-2 degrees ZrCl(eta(2)-S2CPHCy) (2) and Cp-2 degrees ZrCl{eta(2)-SC(PHCY)NPh} (3). Compounds 1-3 were characterized spectroscopically (IR, NMR, MS) and crystal structure determinations were carried out on 1 and 3, showing an eta(2)-bonding mode of the SC(PHCy)NPh (S, N) ligand in the latter. (C) 1997 Elsevier Science Ltd.

引用

页码：2537 / 2545

页数：9

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