Transformations of fac-Re(dmbpy)(CO)3(CO2H) in the presence of carbon dioxide (dmbpy=4,4′-dimethyl-2,2′-bipyridine)

被引：25

作者：

Gibson, DH ^{[1
]}

Yin, XL

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

[2] Univ Louisville, Ctr Chem Catalysis, Louisville, KY 40292 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a902453k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of fac-Re(dmbpy)(CO)(3)(CO2H) 1 or fac, fac-Re(dmbpy)(CO)(3)(CO2)Re(dmbpy)(CO)(3) 2 with CO2, in DMSO or DMF containing small amounts of water, lead to the bicarbonato complex, fac-Re(dmbpy)(CO)(3)[OC(O)OH] 4; the formato complex, fac-Re(dmbpy)(CO)(3)(OCHO) 5, is not a major product in any of these reactions.

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页码：1411 / 1412

页数：2

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