Mannich bases as model compounds for intramolecular hydrogen bonding .1. Solid state structures and molecular calculations

被引：39

作者：

Koll, A ^{[1
]}

Wolschann, P ^{[1
]}

机构：

[1] UNIV VIENNA,INST THEORET CHEM & STRAHLENCHEM,A-1090 VIENNA,AUSTRIA

来源：

MONATSHEFTE FUR CHEMIE | 1996年 / 127卷 / 05期

关键词：

Mannich bases; alkylaminophenol; alkylaminonaphthol; intramolecular hydrogen bond; proton transfer;

D O I：

10.1007/BF00807072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A survey of the structures and the properties of the hydrogen bonds in ortho-aminomethyl-phenols and -naphthols in the solid state is presented. The results are compared with molecular structure calculations. The solid state complexes can exist in the molecular or in zwitterionic form. In the last case, only intermolecular hydrogen bonds forming cyclic dimers or linear chains were detected.

引用

页码：475 / 486

页数：12

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