Sodium removal from titanate nanotubes in electrodeposition process

被引:17
作者
Kim, GS [1 ]
Godbole, VP [1 ]
Seo, HK [1 ]
Kim, YS [1 ]
Shin, HS [1 ]
机构
[1] Chonbuk Natl Univ, Thin Film Technol Lab, Sch Chem Engn, Jellabuk Do 561756, South Korea
关键词
titanate nanotubes; electrodeposition; hydrothermal process;
D O I
10.1016/j.elecom.2006.01.005
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The titanate nanotubes were synthesized using hydrothermal process using commercial titania nanoparticles in 10 M sodium hydroxide solution at -150-200 degrees C, for 30-60 It. Subsequently, the titanate coatings are fabricated on (100) silicon substrates using electrodeposition method, at 80 V and at room temperature. The specimens are characterized using various techniques such as field-emission scanning electron microscope, transmission electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, electron probe microanalysis and X-ray photoelectron spectroscopy. It is observed that sodium content of titanate nanotubes is reduces drastically in electrodeposition process. This is very striking and has far reaching consequences. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:471 / 474
页数:4
相关论文
共 12 条
[1]   TiO2 nanotube-supported ruthenium(III) hydrated oxide:: A highly active catalyst for selective oxidation of alcohols by oxygen [J].
Bavykin, DV ;
Lapkin, AA ;
Plucinski, PK ;
Friedrich, JM ;
Walsh, FC .
JOURNAL OF CATALYSIS, 2005, 235 (01) :10-17
[2]   A novel cation-binding TiO2 nanotube substrate for electro-catalysis and bioelectro-catalysis [J].
Bavykin, DV ;
Milsom, EV ;
Marken, F ;
Kim, DH ;
Marsh, DH ;
Riley, DJ ;
Walsh, FC ;
El-Abiary, KH ;
Lapkin, AA .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (10) :1050-1058
[3]   The surface science of titanium dioxide [J].
Diebold, U .
SURFACE SCIENCE REPORTS, 2003, 48 (5-8) :53-229
[4]   Preparation and structure analysis of titanium oxide nanotubes [J].
Du, GH ;
Chen, Q ;
Che, RC ;
Yuan, ZY ;
Peng, LM .
APPLIED PHYSICS LETTERS, 2001, 79 (22) :3702-3704
[5]  
GODBOLE VP, UNPUB ELECTROCHIM AC
[6]   Electrodeposition of titanium(IV) oxide film from sacrificial titanium anode in I2-added acetone bath [J].
Kamada, K ;
Mukai, M ;
Matsumoto, Y .
ELECTROCHIMICA ACTA, 2002, 47 (20) :3309-3313
[7]   Formation of titanium oxide nanotube [J].
Kasuga, T ;
Hiramatsu, M ;
Hoson, A ;
Sekino, T ;
Niihara, K .
LANGMUIR, 1998, 14 (12) :3160-3163
[8]   Synthesis and characterization of ion-exchangeable titanate nanotubes [J].
Sun, XM ;
Li, YD .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (10) :2229-2238
[9]  
WENG LQ, 2006, IN PRESS J EUROPEAN
[10]   Syntheses of TiO2(B) nanowires and TiO2 anatase nanowires by hydrothermal and post-heat treatments [J].
Yoshida, R ;
Suzuki, Y ;
Yoshikawa, S .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (07) :2179-2185